After you have read the first Digital Comics (Transformers, Star Trek and Astro Boy), Sony has announced that there will be 500 titles at launch.

The European PlayStation blog gives us a list of what should be available on launch day:
2000AD - Judge Dredd, Durham Red, ...
Dysney - Mickey Mouse, Scrooge McDuck, Donald Duck, ...
IDW - Astro Boy, Transformers, Star Trek, Wormwood, ...
Insomnia - Burk & Hare, Cages, Cancer Town
arious - Ape Entertainment, Archie Comics, Dabel Brothers & Red Image 5.
Marvel - X-Men, Captain America, Fantastic 4, Iron Man, The Amazing Spider-Man
Titan - Wallace & Gromit
As you can see, we are far from 500 titles announced but it is a start.

Sony recalls have also implemented a new system called AutoFlow that we showed you a video included in our article Digital Comics: comics offered free by Sony (codes in the news).
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